10.6084/m9.figshare.5861484.v1
Kashish Aggarwal
Kashish
Aggarwal
Anoop Verma
Anoop
Verma
Palak Bansal
Palak
Bansal
Amanjit Singh
Amanjit
Singh
Heterogeneous photo-Fenton and photocatalytic degradation studies of 2-chloro-4-nitrophenol (2Cl4NP) using foundry sand and TiO2 coated cement/clay beads
SciELO journals
2018
Photocatalysis
Photo-Fenton process
Degradation
Cement beads
Clay beads
2018-02-07 02:46:20
Dataset
https://scielo.figshare.com/articles/dataset/Heterogeneous_photo-Fenton_and_photocatalytic_degradation_studies_of_2-chloro-4-nitrophenol_2Cl4NP_using_foundry_sand_and_TiO2_coated_cement_clay_beads/5861484
<div><p>ABSTRACT Cement and clay beads coated with TiO2were used for the photo-degradation and mineralization of 2-chloro-4-nitrophenol (2Cl4NP) along with a heterogeneous solar photo-Fenton process using foundry sand (FS) as the iron source. The degradation process was optimized using slurry photocatalysis where 96% degradation of 2Cl4NP was achieved in 120 min at optimized conditions of C0=50 mgL-1, pH=4, 0.75 gL-1 TiO2 and H2O2= 0.1 mL/200 mL. Degradation of 2Cl4NP was analyzed through HPLC along with UV-Visible spectrophotometer at 266 nm. The degradation of 68% and 52% of 2Cl4NP was attained in fixed-bed photocatalysis using cement and clay beads, respectively. The durability studies of cement and clay beads were carried out in terms of number of recycles. 97.19% degradation was obtained in a solar photo-Fenton process after 105 min at pH=3. Complete mineralization of 2Cl4NP was confirmed through reduction in COD along with the disappearance of the parent compound peak in HPLC chromatograms.</p></div>