10.6084/m9.figshare.6448268.v1
Annalisa Paolone
Annalisa
Paolone
Oriele Palumbo
Oriele
Palumbo
Francesco Trequattrini
Francesco
Trequattrini
Giovanni Battista Appetecchi
Giovanni Battista
Appetecchi
Relaxational Dynamics in the PYR14-IM14 Ionic Liquid by Mechanical Spectroscopy
SciELO journals
2018
DMA
Ionic liquids
conformers
dynamics
2018-06-06 02:44:07
Dataset
https://scielo.figshare.com/articles/dataset/Relaxational_Dynamics_in_the_PYR14-IM14_Ionic_Liquid_by_Mechanical_Spectroscopy/6448268
<div><p>The anelastic spectrum of the N-butyl-N-methyl-pyrrolidinium (trifluoromethanesulfonyl) (nonafluorobutanesulfonyl)imide (PYR14-IM14) is reported for the first time. On cooling, at 4 Kmin-1 the sample undergoes a glass transition around 190 K. In the liquid phase, a thermally activated relaxation process is measured and it is analyzed by means of a modified Debye model. The best fit results indicate that the peak is related to the ion hopping between non-equivalent configurations which are mainly defined by the anion conformer configuration.</p></div>